Fusible plug

A fusible plug is a threaded metal cylinder usually of bronze, brass or gunmetal, with a tapered hole drilled completely through its length. This hole is sealed with a metal of low melting point that flows away if a pre-determined, high temperature is reached. The initial use of the fusible plug was as a safety precaution against low water levels insteam engine boilers, but later applications extended its use to other closed vessels, such as air conditioning systems and tanks for transporting corrosive or liquefied petroleum gasses.

Purpose
A fusible plug operates as a safety valve when dangerous temperatures, rather than dangerous pressures, are reached in a closed vessel. In steam engines the fusible plug is screwed into the crown sheet (the top plate) of the firebox, typically extending about an inch (25mm) into the water space above. Its purpose is to act as a last-resort safety device in the event of the water level falling dangerously low: when the top of the plug is out of the water it overheats, the low-melting-point core melts away and the resulting noisy release of steam into the firebox serves to warn the operators of the danger before the top of the firebox itself runs completely dry, which could result in catastrophic failure of the boiler. The temperature of the flue gases in a steam engine firebox can reach 1000 °F (550 °C), at which temperature copper, from which historically most fireboxes were made, softens to a state which can no longer sustain the boiler pressure and a severe explosion will result if water is not put into the boiler quickly and the fire removed or extinguished. The hole through the plug is too small to have any great effect in reducing the steam pressure and the small amount of water, if any, that passes through it is not expected to have any great impact in quenching the fire.

History
The device was invented in 1803 by Richard Trevithick, the proponent of high-pressure (as opposed to atmospheric) steam engines, in consequence of an explosion in one of his new boilers. His detractors were eager to denounce the whole concept of high-pressure steam, but Trevithick proved that the accident happened because his fireman had neglected to keep the boiler full of water. He publicised his invention widely, without patent, to counter these criticisms.
Experiments
Experiments conducted by the Franklin Institute, Boston, in the 1830s had initially cast doubt on the practice of adding water as soon as the escape of steam through the device was noted. A steam boiler was fitted with a small observation window of glass and heated beyond its normal operating temperature with the water level below the top of the firebox. When water was added it was found that the pressure rose suddenly and the observation glass shattered. The report concluded that the high temperature of the metal had vaporised the added water too quickly and that an explosion was the inevitable result. It was not until 1852 that this assumption was challenged: Thomas Redmond, one of the Institute's own inspectors, specifically ruled out this theory in his investigation into the boiler explosion on the steam ship Redstone on the Ohio River on 3 April that year.A 1907 investigation in Wales came to a similar conclusion: a steam locomotive belonging to the Rhymney Railway was inadvertently sent out with its safety valves wrongly assembled. The pressure in the boiler built up to the extent that the injectors failed; the crown sheet became uncovered, was weakened by the heat of the fire and violently blew apart. The investigation, led by Colonel Druitt of theRailway Inspectorate, dismissed the theory that the enginemen had succeeded in starting the injectors and that the sudden flood of cold water had caused such a generation of steam that the boiler burst. He quoted the results of experiments by theManchester Steam Users' Association, a national boiler certification and insurance body, that proved that the weight of copper present (considered with its specific heat) was insufficient to generate enough steam to raise the boiler pressure at all. Indeed, the addition of cold water had caused the pressure to fall. From then on it was accepted that the correct action in the event of the operation of the fusible plug was to add water.

Cored fusible plugs

The original design was a simple solid plug filled with a slug of low-melting-point alloy. When this melts, it first melts as a narrow channel through the plug. Steam and water immediately begins to escape through this. The cored fusible plug was developed in the 1860s to give a wide opening as soon as the alloy softens. This version has a solid brass or bronze centre, soldered into place by a layer of the low-melting-point alloy. When overheated, the plug does not release any steam or water until the alloy melts sufficiently to release the centre plug. The plug now fails dramatically, opening its entire bore immediately. This full-bore jet is then more likely to be noticed

Un-noticed melted plugs
A drawback to the device was found on 7 March 1948, when the firebox crown sheet ofPrincess Alexandra, a Coronation Pacific of the London, Midland and Scottish Railway, failed while hauling a passenger train from Glasgow to London. Enquiries established that both water gauges were defective and on a journey earlier that day one or both of the fusible plugs had melted, but this had gone unnoticed by the engine crew because of the strong draught carrying the escaping steam away from them.

Alloy composition
Investigation showed the importance of the alloy on plug ageing. Alloys were initially favoured as they offered lower eutecticmelting points than pure metals. It was found though that alloys aged poorly and could encourage the development of a matrix of oxides on the water surface of the plug, this matrix having a dangerously high melting point that made the plug inoperable. In 1888 the US Steamboat Inspection Service made a requirement that plugs were to be made of pure banca tin and replaced annually. This avoided lead and also zinc contamination. Zinc contamination was regarded as so serious a problem that the case of the plugs was also changed from brass (a copper-zinc alloy) to a zinc-free copper-tin bronze, to avoid the risk of zinc migrating from the housing into the alloy plug
Plug ageing
In the 1920s investigations by the U.S. Bureau of Standards, in conjunction with the Steamboat Inspection Service, found that in use encrustation and oxidation above the fusible core can increase melting point of the device and prevent it from working when needed: melting points in excess of 2000 °F (1100 °C) in used examples have been found. Typical current practice in locomotives requires new plugs to be inspected after "15 to 30 working days (dependent upon water condition and use of locomotive) or at least once every six months," depending on the boiler operating pressure and temperature

Other applications
The principle of the fusible plug is also applied to the transport of liquefied petroleum gases, where fusible plugs (or small, exposed patches of the containers' lining membrane) are designed to melt or become porous if too high a temperature is reached: a controlled release, at a typical temperature of 250 °F (120 °C), is preferable to an explosive release (a "BLEVE") at a higher temperature. Corrosive gas containers, such as those used for liquid chlorine, are fitted with one or more fusible plugs with an operating temperature of about 158 to 165 °F (70–74 °C)
Fusible plugs are common in aircraft wheels, typically in larger or high-performance aircraft. The very large thermal loads imposed by abnormal landing and braking conditions (an RTO notably) can cause already high pressure in the tyres to rise to the point that the tyre might burst, so fusible plugs are used as a relief mechanism. The vented gas may be directed to cool the braking surfaces.

Fusible plugs are sometimes fitted to the receivers of air compressors as a precaution against the ignition of any lubricating oil vapour that might be present. Should the action of the compressor heat the air above a safe temperature the core will melt and release the pressure.

Automobile air conditioning systems were commonly fitted with fusible plugs, operating at 100–110 °C, but from concerns about the environmental effects of any released refrigerant gas this function has been taken over by an electrical switch.

A patented type of fireproof safe uses a fusible plug to douse its contents with water if the external temperature gets too high.

Water Softener

Water softening is the reduction of the concentration of calcium, magnesium, and certain other metal cations in hard water. These "hardness ions" can cause a variety of undesired effects includinginterfering with the action of soaps, the build up of limescale, which can foul plumbing, and galvanic corrosion. Conventional water-softening appliances intended for household use depend on an ion-exchange resin in which hardness ions are exchanged for sodium ions. Water softening may be desirable where the source of water is hard. However, hard water also conveys some benefits to health by providing dietary calcium and magnesium and reducing the solubility of potentially toxic metal ions such as lead and copper.

Methods for water softening

Water softening methods mainly rely on the removal of Ca2+ and Mg2+ from a solution or the sequestration of these ions, i.e. binding them to a molecule that removes their ability to form scale or interfere with soaps. Removal is achieved by ion exchange and by precipitation methods. Sequestration entails the addition of chemical compounds called sequestration (or chelating) agents.

Since Ca2+ and Mg2+ exist as nonvolatile salts, they can be removed by distilling the water, but distillation is too expensive in most cases (rainwater is soft because it is, in effect, distilled)
Ion-exchange resin devices

Ion-exchange materials contain sodium ions (Na+) that are electrostatically bound and that readily are replaced by hardness ions such as Ca2+ and Mg2+. Ion exchange resins are organic polymers containing anionic functional groups to which the Na+ is bound. Minerals called zeolites also exhibit ion-exchange properties; these minerals are widely used in laundry detergents.

How it works

The water to be treated passes through a bed of the resin. Negatively-charged resins absorb and bind metal ions, which are positively charged (2RNa(s)+M2+(aq)=R2M(s)+2Na+(aq)(M=Mg or Ca)). The resins initially contain univalent (1+) ions, most commonly sodium, but sometimes also hydrogen (H+) or potassium (K+). Divalent calcium and magnesium ions in the water replace these univalent ions, which are released into the water. The "harder" the water, the more hydrogen, sodium or potassium ions are released from the resin and into the water.

Resins are also available to remove carbonate, bi-carbonate and sulphate ions which are absorbed and hydroxyl ions released from the resin. Both types of resin may be provided in a single water softener. This method is called the ion exchange method.
Lime softening

Lime softening, also known as Clark's process[1], is a type of water treatment used for water softening. In the USA, it is used primarily in the Midwest, Florida and Texas. It utilizes the addition of lime (calcium hydroxide) to remove hardness (calcium and magnesium) ions by precipitation. The process is also effective at removing a variety of microorganisms and dissolved organic matter[2].
 Softening can be achieved by adding lime in the form of Ca(OH)2, which reacts first with CO2 to form calcium carbonate precipitate, reacts next with multivalent cations to remove carbonate hardness, then reacts with anions to replace the non-carbonate hardness due to multivalent cations with non-carbonate hardness due to calcium. The process requires recarbonation through the addition of carbon dioxide to lower the pH which is raised during the initial softening process.[3]

As lime is added to raw water, the pH is raised and the equilibrium of carbonate species in the water is shifted. Dissolved carbon dioxide (CO2) is changed in to bicarbonate (HCO3-) and then carbonate (CO32-). This action causes calcium carbonate to precipitate due to exceeding the solubility product. Additionally, magnesium can be precipitated as magnesium hydroxide in a double displacement reaction.

The process is unique in that both the calcium (and to an extent magnesium) in the raw water as well as the calcium added with the lime are both precipitated. This is in contrast to ion exchange softening where sodium is exchanged for calcium and magnesium ions. In lime softening, there is a substantial reduction in total dissolved solids (TDS). In ion exchange softening (sometimes referred to as zeolite softening), there is no significant change in the level of TDS.

Lime softening can be used to remove iron, manganese, radium and arsenic from water.


Regeneration

The resin's capacity is gradually exhausted and eventually it contains only divalent ions (e.g., Mg2+ and Ca2+ for cation exchange resins, and SO42- for anion exchange resins). At this stage, the resin must be regenerated. If a cationic resin is used (to remove calcium and magnesium ions) then regeneration is usually effected by passing a concentrated brine, usually of sodium chloride or potassium chloride, or hydrochloric acid solution through them. For anionic resins, regeneration typically uses a solution of sodium hydroxide (lye) or potassium hydroxide. The salts used for regeneration are released into the soil or sewer.

In industrial scale water softening plants, the effluent flow from re-generation process can precipitate scale that can interfere with sewerage systems.

Effects of sodium

For people on a low-sodium diet, the increase in sodium levels (for systems releasing sodium) in the water can be significant, especially when treating very hard water. For example:

A person who drinks two litres (2L) of softened, extremely hard water (assume 30 gpg) will consume about 480 mg more sodium (2L x 30 gpg x 8 mg/L/gpg = 480 mg), than if unsoftened water is consumed.

This amount is significant. The American Heart Association (AHA) suggests that the 3 percent of the population who must follow a severe, salt-restricted diet should not consume more than 400 mg of sodium a day. AHA suggests that no more than 10 percent of this sodium intake should come from water. The EPA’s draft guideline of 20 mg/L for water protects people who are most susceptible.[3] Most people who are concerned with the added sodium in water generally have one tap in the house that bypasses the softener, or have a reverse osmosis unit installed for the drinking water and cooking water, which was designed for desalinisation of sea water. Potassium chloride can also be used instead of sodium chloride, which would have the added benefit of helping to lower blood pressure, although costly. However, elevated potassium levels are dangerous for people with impaired kidney function: it can lead to complications such as cardiac arrhythmia.

Effects of soap in hard water

Hard water contains calcium and magnesium ions. Water softeners remove those ions by exchanging them for sodium or potassium ions. The slippery feeling experienced when using soap with soft water occurs because soaps tend to bind to fats in the surface layers of skin, making soap molecules difficult to remove by simple dilution. In contrast, in hard-water areas the rinse water contains calcium and/or magnesium ions which form insoluble stearates (or their equivalents), effectively removing the residual soap from the skin but potentially leaving a surface coating of insoluble stearates which may be seen as scum.[4]


Water softener FAQ Frequently Asked Questions

1. Hard water

1.1 What is hard water?

When water is referred to as 'hard' this simply means, that it contains more minerals than ordinary water. These are especially the minerals calcium and magnesium. The degree of hardness of the water increases, when more calcium and magnesium dissolves.
Magnesium and calcium are positively charged ions. Because of their presence, other positively charged ions will dissolve less easily in hard water than in water that does not contain calcium and magnesium.
This is the cause of the fact that soap doesn't really dissolve in hard water.

1.2 Which industries attach value to hardness of water?

In many industrial applications, such as the drinking water preparation, in breweries and in sodas, but also for cooling- and boiler feed water the hardness of the water is very important.

2. Water softening

2.1 What is water softening?

When water contains a significant amount of calcium and magnesium, it is called hard water. Hard water is known to clog pipes and to complicate soap and detergent dissolving in water.
Water softening is a technique that serves the removal of the ions that cause the water to be hard, in most cases calcium and magnesium ions. Iron ions may also be removed during softening.
The best way to soften water is to use a water softener unit and connect it directly to the water supply.

2.2 What is a water softener?

A water softener is a unit that is used to soften water, by removing the minerals that cause the water to be hard.

2.3 Why is water softening applied?

Water softening is an important process, because the hardness of water in households and companies is reduced during this process.
When water is hard, it can clog pipes and soap will dissolve in it less easily. Water softening can prevent these negative effects.
Hard water causes a higher risk of lime scale deposits in household water systems. Due to this lime scale build-up, pipes are blocked and the efficiency of hot boilers and tanks is reduced. This increases the cost of domestic water heating by about fifteen to twenty percent.
Another negative effect of lime scale is that it has damaging effects on household machinery, such as laundry machines.
Water softening means expanding the life span of household machine, such as laundry machines, and the life span of pipelines. It also contributes to the improved working, and longer lifespan of solar heating systems, air conditioning units and many other water-based applications.

2.4 What does a water softener do?

Water softeners are specific ion exchangers that are designed to remove ions, which are positively charged.
Softeners mainly remove calcium (Ca2+) and magnesium (Mg2+) ions. Calcium and magnesium are often referred to as 'hardness minerals'.
Softeners are sometimes even applied to remove iron. The softening devices are able to remove up to five milligrams per litre (5 mg/L) of dissolved iron.
Softeners can operate automatic, semi-automatic, or manual. Each type is rated on the amount of hardness it can remove before regeneration is necessary.

A water softener collects hardness minerals within its conditioning tank and from time to time flushes them away to drain.
Ion exchangers are often used for water softening. When an ion exchanger is applied for water softening, it will replace the calcium and magnesium ions in the water with other ions, for instance sodium or potassium. The exchanger ions are added to the ion exchanger reservoir as sodium and potassium salts (NaCl and KCl).

2.5 How long does a water softener last?

A good water softener will last many years. Softeners that were supplied in the 1980's may still work, and many need little maintenance, besides filling them with salt occasionally.

3. Softening salts

3.1 Which types of salt are sold for application in a water softener?

For water softening, three types of salt are generally sold:
- Rock salt
- Solar salt
- Evaporated salt

Rock salt as a mineral occurs naturally in the ground. It is obtained from underground salt deposits by traditional mining methods. It contains between ninety-eight and ninety-nine percent sodium chloride. It has a water insolubility level of about 0.5-1.5%, being mainly calcium sulphate. Its most important component is calcium sulphate.
Solar salt as a natural product is obtained mainly through evaporation of seawater. It contains 85% sodium chloride. It has a water insolubility level of less than 0.03%. It is usually sold in crystal form. Sometimes it is also sold in pellets.
Evaporated salt is obtained through mining underground salt deposits of dissolving salt. The moisture is then evaporated, using energy from natural gas or coal. Evaporated salt contains between 99.6 and 99.99% sodium chloride.

3.2 Should we use rock salt, evaporated salt or solar salt in a water softener?

Rock salt contains a lot of matter that is not water-soluble. As a result, the softening reservoirs have to be cleaned much more regularly, when rock salt is used. Rock salt is cheaper than evaporated salt and solar salt, but reservoir cleaning may take up a lot of your time and energy.

Solar salt contains a bit more water-insoluble matter than evaporated salt. When one makes a decision about which salt to use, consideration should be given to how much salt is used, how often the softener needs cleanout, and the softener design. If salt usage is low, the products could be used alternately.
If salt usage is high, insoluble salts will build up faster when using solar salt. Additionally, the reservoir will need more frequent cleaning. In that case evaporated salt is recommended.

3.3 Is it harmful to mix different kinds of salt in a water softener?

It is generally not harmful to mix salts in a water softener, but there are types of softeners that are designed for specific water softening products. When using alternative products, these softeners will not function well.
Mixing evaporated salt with rock salt is not recommended, as this could clog the softening reservoir. It is recommended that you allow your unit to go empty of one type of salt before adding another to avoid the occurrence of any problems.

3.4 How often should one add salt to a softener?

Salt is usually added to the reservoir during regeneration of the softener. The more often a softener is regenerated, the more often salt needs to be added.
Usually water softeners are checked once a month. To guarantee a satisfactory production of soft water, the salt level should be kept at least half-full at all times.

3.5 How come water sometimes does not become softer when salt is added?

Before salt starts working in a water softener it needs a little residence time within the reservoir, since the salt is dissolving slowly. When one immediately starts regeneration after adding salt to the reservoir, the water softener may not work according to standards.
When the water softening does not take place it could also indicate softener malfunction, or a problem with the salt that is applied.

4. Softening costs

4.1 How much does a water softener cost?

Some softeners are more efficient than others and as a result the prizes may differ. There are time operated softeners and water meter-controlled softeners available. The water meter-controlled units produce the softest water per pound of salt.
Some softeners work on electricity, but some more recent water softeners use waterpower. Costs of a water softener greatly depend upon the type of water softener and the type of energy that is used, but also upon the hardness of the water that needs softening and the water use. When the water is very hard and it is used heavily, the costs of softening will rise.

Generally the costs of a water softener can vary between € 0,20 and € 0,40 a day.
The costs of water softeners are usually far outweighed by the benefits and cost savings obtained, through using softened water.

4.2 How much does a water softener cost during operation?

The running cost is merely the cost of salt. This is likely to be around € 1,95 per person in the household in a month.

5. Softening drinking water

5.1 Do water-producing companies always produce softened water?

Although water-producing companies do have the opportunity to produce softened water, they will not always do so. A water producing company only has to add a water softener in its water purification system, to produce softened water cheaply.
But than consumers would not be able to have the choice to drink un-softened water.
Hard water problems are most likely to occur when water is heated. As a result, hard water causes few problems to the water supplying companies, especially when only cold water runs through their pipes.

5.2 Is softened water safe to drink?

Softened water still contains all the natural minerals that we need. It is only deprived off its calcium and magnesium contents, and some sodium is added during the softening process. That is why in most cases, softened water is perfectly safe to drink. It is advisable that softened water contains only up to 300mg/L of sodium.
In areas with very high hardness the softened water must not be used for the preparation of baby-milk, due to the high sodium contant after the softening process has been carried out.

5.3 Can salt from softening installations enter drinking water?

Salt does not have the opportunity to enter drinking water through softening installations.
The only purpose of salt in a water softener is to regenerate the resin beads that take the hardness out of water.
5.4 How much sodium does one absorb from softened water?

The sodium uptake through softened water depends on the hardness of the water. Averagely, less than 3% sodium uptake comes from drinking softened water.
Estimates say that a person consumes about two to three teaspoons of salt a day, from various sources. Assuming a daily intake of five grams of sodium through food and the consumption of three quarts of water, the contribution of sodium (Na+) in the water from the home water softening process, is minimal compared to the total daily intake of many sodium-rich foods.

5.5 Will softening drinking water deprive it of essential minerals?

Softening will not deprive water of its essential minerals. Softening only deprives drinking water of minerals that cause the water to be hard, such as calcium, magnesium and iron.

6. Softeners maintenance

6.1 When does a softener resin need replacement?

When the water does not become soft enough, one should first consider problems with the salt that is used, or mechanical malfunctions of softener components. When these elements are not the cause of the unsatisfactory water softening, it may be time to replace the softener resin, or perhaps even the entire softener.
Through experience we know that most softener resins and ion exchanger resins last about twenty to twenty-five years.

6.2 Does a softener brine tank need cleaning?

Usually it is not necessary to clean out a brine tank, unless the salt product being used is high in water-insoluble matter, or there is a serious malfunction of some sort.
If there is a build-up of insoluble matter in the resin, the reservoir should be cleaned out to prevent softener malfunction.

6.3 What is 'mushing' and why should we avoid it?

When loosely compacted salt pellets or cube-style salt is used in a resin, it may form tiny crystals of evaporated salt, which are similar to table salt. These crystals may bond, creating a thick mass in the brine tank. This phenomenon, commonly known as 'mushing', may interrupt brine production. Brine production is the most important element for refreshing of the resin beads in a water softener. Without brine production, a water softener is not able produce soft water.

7. Softener operational questions

7.1 Can brine from softeners damage a septic tank?

The Water Quality Association has performed studies on this subject. These studies have indicated that a properly placed septic tank that works adequately cannot be damaged by brine that is discharged from a water softener. And softened water can sometimes even help reduce the amount of detergents discharged into a septic tank.

7.2 Can a water softener be used with lead pipes?

Lead pipe systems have to be replaced, before softened water can flow through them. Although lead pipe systems in hard water areas may not cause a problem, it is advisable to replace them anyway. When naturally or artificially softened water ends up in these lead pipe systems, it may cause the pickup of lead.
Yes, although the measurement system is mainly applied in industrial water softeners.
The Testomat inline water hardness instrument

8. Softening in households

8.1 Can a water softener be taken along during moving?

With modern water softeners, it is very possible to take them along during moving. Installation techniques involve quick fitting connections, similar to those used for laundry machines.
All that has to be done is closing off the inlet and outlet valves of the softener and open up the bypass valve, allowing hard water to flow to the storage tank and household taps. After that the softener can be disconnected, moved to its new location and placed there.

8.2 Can waste from a water softener be discharged directly in the garden?

As brine alters the osmotic pressure that plants rely upon to regulate water needs, direct discharge of either sodium or potassium chloride brine should be avoided.

8.3 Is softened water any help for dry skin conditions?

There are cases to be noted, in which people with dry skin conditions have benefited from water softening, because soft water is kinder to the hair and skin.

 

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